In:
European Journal of Organic Chemistry, Wiley, Vol. 2013, No. 19 ( 2013-07), p. 3974-3977
Abstract:
Upon treatment with sodium azide in DMF, bisalkynes undergo chemoselective [3+2] cycloaddition followed by oxidative cleavage of the other alkyne unit by atmospheric oxygen. The neighboring triazoloyl ion is found to assist the cleavage process ultimately to deliver an acid and an aldehyde.
Type of Medium:
Online Resource
ISSN:
1434-193X
,
1099-0690
DOI:
10.1002/ejoc.v2013.19
DOI:
10.1002/ejoc.201300441
Language:
English
Publisher:
Wiley
Publication Date:
2013
detail.hit.zdb_id:
1475010-7