In:
European Journal of Organic Chemistry, Wiley, Vol. 2016, No. 26 ( 2016-09), p. 4473-4475
Abstract:
A very rare crystal was prepared consisting of a 2D aromatic (toluene) together with a weakly coordinating 3D aromatic ( closo ‐1‐CB 11 H 12 – ) and a hydronium ion, and this crystal was analyzed by using X‐ray diffraction and high‐level quantum‐mechanical calculations. The nature of the crystal arrangement made it possible to detect the frozen π complex that would originate during protonation of toluene by the acidic hydronium ion.
Type of Medium:
Online Resource
ISSN:
1434-193X
,
1099-0690
DOI:
10.1002/ejoc.v2016.260
DOI:
10.1002/ejoc.201600912
Language:
English
Publisher:
Wiley
Publication Date:
2016
detail.hit.zdb_id:
1475010-7