In:
European Journal of Organic Chemistry, Wiley, Vol. 2019, No. 38 ( 2019-10-17), p. 6504-6509
Kurzfassung:
The three‐ and four‐component reactions of [60]fullerene with triethylamine/diethylamine and aldehydes affording 2‐arylvinyl‐substituted fulleropyrrolidines in high stereoselectivity have been achieved. Depending on the reaction conditions, cis ‐ and trans ‐fulleropyrrolidines can be stereoselectively synthesized. The thermodynamically stable cis ‐fulleropyrrolidines can be obtained by rearrangement of the kinetically formed trans ‐fulleropyrrolidines. A plausible reaction mechanism is proposed to elucidate the formation of fulleropyrrolidines.
Materialart:
Online-Ressource
ISSN:
1434-193X
,
1099-0690
DOI:
10.1002/ejoc.v2019.38
DOI:
10.1002/ejoc.201901133
Sprache:
Englisch
Verlag:
Wiley
Publikationsdatum:
2019
ZDB Id:
1475010-7