In:
European Journal of Organic Chemistry, Wiley, Vol. 2022, No. 9 ( 2022-03-07)
Abstract:
An efficient protocol for the synthesis of 3‐ethynyl‐2‐aryl‐bicyclo[3.1.0]hexenes through a gold‐catalyzed enyne cyclization was established in this work. Depending on the specific substitution pattern, unusual cationic rearrangements of the corresponding gold carbene were revealed, leading to either cyclohexadienes or 5,9‐methanobenzo[8] annulene derivatives, respectively.
Type of Medium:
Online Resource
ISSN:
1434-193X
,
1099-0690
DOI:
10.1002/ejoc.v2022.9
DOI:
10.1002/ejoc.202200027
Language:
English
Publisher:
Wiley
Publication Date:
2022
detail.hit.zdb_id:
1475010-7