In:
Journal of Computational Chemistry, Wiley, Vol. 44, No. 25 ( 2023-09-30), p. 1986-1997
Kurzfassung:
The surfaces of waimirite β‐have been studied for their fluorine and chlorine versus water affinity. Bonding patterns of HF, HCl, and chemically adsorbed onto surfaces of (010), (100), (011), and (101) have been quantified by density functional theory applying energy decomposition analysis. We found that the adsorption of is dominated by about 65% of electrostatics, which causes a low surface sensitivity and weak interactions. On the contrary, the adsorptions of HF and HCl are driven by strong hydrogen bonds resulting in a highly surface‐dependent ratio of 30–60% electrostatic versus orbital contribution. Among the stoichiometric surfaces, the shortest and strongest hydrogen bonds and consequently most covalent bonding patterns are found within HCl. However, when including the preparation energy, each surface favors the adsorption of HF over HCl, which reproduces the higher affinity of yttrium towards fluoride over chloride, previously known for solutions, also for the solid state.
Materialart:
Online-Ressource
ISSN:
0192-8651
,
1096-987X
Sprache:
Englisch
Verlag:
Wiley
Publikationsdatum:
2023
ZDB Id:
1479181-X