In:
Journal of Heterocyclic Chemistry, Wiley, Vol. 59, No. 8 ( 2022-08), p. 1435-1440
Abstract:
A photochemically promoted intramolecular cyclization of aryl‐, vinyl‐, and alkyliodo allenes has been developed. The optimal conditions employed [Ir(ppy) 2 (dtbbpy)]PF 6 (1 mol%) as catalyst affording products with high exo selectivity in moderate to good yields. Chiral substrates showed diastereoselectivity of up to 95/5 favoring trans product.
Type of Medium:
Online Resource
ISSN:
0022-152X
,
1943-5193
Language:
English
Publisher:
Wiley
Publication Date:
2022
detail.hit.zdb_id:
2042274-X
