In:
Journal of Polymer Science Part A: Polymer Chemistry, Wiley, Vol. 45, No. 6 ( 2007-03-15), p. 1134-1142
Abstract:
Bis(salicylaldiminate)copper(II) complexes, when activated with methylaluminoxane, catalyzed the homo‐ and copolymerizations of ethylene and methyl methacrylate (MMA). The activity in the MMA homopolymerization was influenced by the electronic and steric characteristics of the Cu(II) precursors as well as the cocatalyst concentration. The same systems revealed modest activity also in the homopolymerization of ethylene, giving a highly linear polyethylene, and in its copolymerization with MMA. These copolymers exhibited a very high content of polar groups (MMA units 〉 70 mol %) and were characterized by a high molecular weight and polydispersity. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1134–1142, 2007
Type of Medium:
Online Resource
ISSN:
0887-624X
,
1099-0518
Language:
English
Publisher:
Wiley
Publication Date:
2007
detail.hit.zdb_id:
3004641-5
detail.hit.zdb_id:
1473076-5