In:
ChemistrySelect, Wiley, Vol. 2, No. 35 ( 2017-12-11), p. 11673-11676
Abstract:
Two lead complexes, Tetrakis(μ 3 ‐(4‐methyl‐3‐nitrophenyl imido lead (II))) 1 , and Bis(2‐nitrodiphenyl amido lead(II)) 2 , were prepared by protolysis of bis(bis(trimethylsilyl)amido)lead(II) with two compounds relevant to double‐base propellant stabilizers: 2‐nitrodiphenylamine (NDPA) and 4‐methyl‐3‐nitroaniline. Crystal structures were determined as tetrahydrofuran solvates, and exhibit a number of unusual geometric features, including low lead coordination number. Heats of combustion and formation were determined using bomb calorimetry and converted to energy density using crystallographic densities. Compound 1 has an energy density of 30 MJ/L, whereas 2 was 38.2 MJ/L.
Type of Medium:
Online Resource
ISSN:
2365-6549
,
2365-6549
DOI:
10.1002/slct.201701791
Language:
English
Publisher:
Wiley
Publication Date:
2017
detail.hit.zdb_id:
2844262-3
