In:
Small, Wiley, Vol. 11, No. 44 ( 2015-11), p. 5940-5948
Kurzfassung:
A novel 3D nanoarchitecture comprising in situ‐formed N‐doped CoNi alloy‐encapsulated carbon nanotubes (CoNi‐NCNTs) grown on N‐doped porous carbon nanosheets (NPCNs) is designed and constructed for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). When evaluated as an electrocatalyst for ORR, the hybrid shows efficient catalytic activity, high selectivity, superior durability, and strong tolerance against methanol crossover compared with the commercial Pt/C catalyst. Such good oxygen reduction reaction performance is comparable to most of the previously reported results and the synergistic effect is found to boost the catalytic performance. Moreover, the constructed hybrid exhibits an excellent ORR activity with a current density of 10 mA cm −2 at 1.59 V and an onset potential of 1.57 V, even beyond the state‐of‐the‐art Ir/C catalyst in alkaline media. The enhancement in electrochemical performance can be attributed to the unique morphology and defect structures, high porosity, good conductive networks, and strongly interacting CoNi‐NCNT and NPCN in the hybrid. These results suggest the possibility for the development of effective nanocarbon electrocatalysts to replace commercial noble metal catalysts for direct use in fuel cells and water splitting devices.
Materialart:
Online-Ressource
ISSN:
1613-6810
,
1613-6829
DOI:
10.1002/smll.201502297
Sprache:
Englisch
Verlag:
Wiley
Publikationsdatum:
2015
ZDB Id:
2168935-0