In:
Small Science, Wiley, Vol. 2, No. 2 ( 2022-02)
Abstract:
Mixtures of nonfullerene acceptors (NFAs) are prepared to fine‐tune bulk heterojunction (BHJ) thin‐film morphologies. The acceptor phase resulting from these mixtures has unique physical properties with excellent optoelectronic processes that dictate the output of organic photovoltaic (OPV) devices. Remarkable short‐circuit current densities ( J SC ) and fill factors (FFs) are achieved due to the formation of better crystalline fibrils that suppress geminate recombination, leading to improved charge transport with enhanced crystallinity and aligned cascading energy levels confirm efficient exciton diffusion and dissociation, yielding more effective exciton recycling. The decreased Urbach energy and suppressed energetic disorder account for the improvement in the open‐circuit voltage ( V OC ). A maximum power conversion efficiency of 17.86% is obtained, underscoring the importance of using specific material interactions to produce a suitable morphology and manage energy loss, resulting in ideal organic solar cell (OSC) devices.
Type of Medium:
Online Resource
ISSN:
2688-4046
,
2688-4046
DOI:
10.1002/smsc.202100092
Language:
English
Publisher:
Wiley
Publication Date:
2022
detail.hit.zdb_id:
3042766-6