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Synthese und Kristallstruktur der spirocyclischen Gallium‐ und Indium‐Chalkogen‐Heterocyclen [(Me 2 Ga) 6 S(SSiMe 3 ) 4 ], [(Me 2 Ga) 6 Se(SeSiMe 3 ) 4 ] und [(Me 2 In) 6 S(SSiMe 3 ) 4 ]

Kluge, Oliver ; Puidokait, Martin ; Biedermann, Ralf ; [et al.]

Wiley ; 2007

In: Zeitschrift für anorganische und allgemeine Chemie Vol. 633, No. 13-14 ( 2007-10), p. 2138-2140

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In: Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 633, No. 13-14 ( 2007-10), p. 2138-2140

Abstract: Synthesis and Crystal Structures of Spirocyclic Gallium and Indium Chalcogen Heterocycles [(Me 2 Ga) 6 S(SSiMe 3 ) 4 ], [(Me 2 Ga) 6 Se(SeSiMe 3 ) 4 ] and [(Me 2 In) 6 S(SSiMe 3 ) 4 ] The isostructural title compounds [(Me 2 M) 6 E(ESiMe 3 ) 4 ] (M = Ga, In; E = S, Se) crystallize in space group C 2/ c and consist of two M 3 E 3 rings in twist conformation, sharing a common chalcogen atom. The reactivity of the remaining M–CH 3 and E–SiMe 3 bonds can be used for further reactions.

Type of Medium: Online Resource

ISSN: 0044-2313 , 1521-3749

URL: Issue

URL: Article

DOI: 10.1002/zaac.v633:13/14

DOI: 10.1002/zaac.200700373

RVK:

VA 8102

Language: English

Publisher: Wiley

Publication Date: 2007

detail.hit.zdb_id: 201094-X