In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 639, No. 7 ( 2013-06), p. 1090-1094
Abstract:
The reaction of the complex [{Ir(μ‐Cl)(ptpy) 2 } 2 ] ( 1 ) with oxamide in methanol in the presence of sodium methylate as the base was investigated. During the reaction the new complex [Ir 2 (μ 2 ‐oxamidato‐ N , N′ , O , O′ )(ptpy) 4 ] ( 2) , ptpy = 2‐(p‐tolyl)pyridinato was obtained. The molecular structure of compound 2 was determined by an X‐ray diffraction study. 2 crystallized from dichloromethane/methanol as a dihydrate in the orthorhombic space group Pbcm. This new compound displays intense green phosphorescence, with φ PL = 60 %, stemming from the lowest triplet state of the 3 MLCT/LC character.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.201300069
Language:
English
Publisher:
Wiley
Publication Date:
2013
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X