In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 642, No. 4 ( 2016-02), p. 294-298
Kurzfassung:
In this paper, the syntheses of antimony and nitrogen containing interpnictogen compounds are described. Using t Bu 2 SbCl as reagent, a tert ‐butyl‐substituted stibano amine t Bu 2 SbN(H) t Bu ( 1 ), an isopropyl‐substituted interpnictogen t Bu 2 SbN(H) i Pr ( 2 ), and a primary stibano amine t Bu 2 SbNH 2 ( 3 ) are obtained. Condensation of compound 3 leads to compound ( t Bu 2 Sb) 2 NH ( 4 ) with elimination of ammonia. All compounds were characterized by 1 H, 13 C, 15 N NMR spectroscopy, mass spectrometry, and IR spectroscopy. These interpnictogens represent a new class of single‐source precursors for MOVPE process. The primary amine 3 reacts with AlEt 3 and GaEt 3 to form previously unknown stibane‐substituted [ t Bu 2 SbN(H) M Et 2 ] 2 ring compounds [ M = Al ( 5 ), M = Ga ( 6 )], which were characterized by different spectroscopic methods. Moreover, compounds 4 and 6 could be analyzed by X‐ray diffraction.
Materialart:
Online-Ressource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.201500787
Sprache:
Englisch
Verlag:
Wiley
Publikationsdatum:
2016
ZDB Id:
201094-X
ZDB Id:
1481139-X
