In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 643, No. 22 ( 2017-12-04), p. 1793-1800
Abstract:
The new zincophosphate of chemical formula [C 6 H 10 N 2 ][ZnP 2 O 8 H 2 ] · 0.6H 2 O was hydrothermally synthesized with p ‐phenylenediamine as structure‐directing agent. The title compound crystallizes in the trigonal symmetry (proposed space group P 3 m 1), where inorganic zincophosphate chains form layers due to the half occupancy of the unique crystallographic zinc site. The layers are separated from each other by p ‐phenylenediammonium dications with hydrogen bonding scheme involving the ammonium protons that reveals a pillar‐like 3D structure aspect. The compound was characterized by powder X‐ray diffraction, multinuclear solid‐state NMR, scanning electron microscopy, chemical analysis, and thermogravimetric analysis.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.v643.22
DOI:
10.1002/zaac.201700189
Language:
English
Publisher:
Wiley
Publication Date:
2017
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X