In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 646, No. 15 ( 2020-08-14), p. 1336-1341
Abstract:
The exploration of highly efficient Pd/MOF heterogeneous catalyst system for the Suzuki–Miyaura cross‐coupling (SMC) reactions of aryl chlorides is still challenging. Herein, a PdCl 2 /UiO‐67‐bpydc was successfully synthesized by immobilizing a low amount of PdCl 2 onto the zirconium‐based MOF (UiO‐67‐bpydc). PdCl 2 /UiO‐67‐bpydc showed excellent catalytic performance and good recycle ability for the SMC reaction of aryl chlorides under an ambient condition. Furthermore, PdCl 2 /UiO‐67‐bpydc retains the high catalytic activity even after five cycles, and exhibited excellent substrate size selectivity.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.v646.15
DOI:
10.1002/zaac.202000132
Language:
English
Publisher:
Wiley
Publication Date:
2020
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X