In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 647, No. 2-3 ( 2021-02-11), p. 119-125
Abstract:
Cs 8 B 8 Si 38 is obtained by high‐pressure high‐temperature synthesis at p =8 GPa and T =1273 K. The new compound (space group Pm n ; a =10.0312(3) Å) is the third example for a clathrate‐I borosilicide after the potassium and rubidium varieties, respectively. The phase slowly deteriorates in air and moisture but is thermally stable up to 1050 K at ambient pressure. [Cs + ] 8 [B – ] 8 [Si 0 ] 38 is electronically balanced, diamagnetic, and shows semiconducting behavior.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.v647.2-3
DOI:
10.1002/zaac.202000400
Language:
English
Publisher:
Wiley
Publication Date:
2021
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X