In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 647, No. 18 ( 2021-09-27), p. 1849-1854
Abstract:
The reaction of Tl(C 5 H 5 ) with Ag[C 5 (CN) 5 ] gives unexpectedly the title compound. Its crystal structure shows a dimeric [Tl 2 [C 5 (CN) 2 ] 2 ] forming the asymmetric unit. These units are connected to “layers” perpendicular to the a axis with formation of numerous 4‐, 9‐ and 14 membered rings, with the Tl ions using three nitrile functions from three different ligands. These layers are connected in a direction with each Tl ion coordinating to three more nitrile functions and additional weak delocalized η 5 or η 3 interactions with a cyclopentadienyl ring.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.v647.18
DOI:
10.1002/zaac.202100244
Language:
English
Publisher:
Wiley
Publication Date:
2021
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X