In:
Chemical Communications, Royal Society of Chemistry (RSC), Vol. 57, No. 75 ( 2021), p. 9562-9565
Abstract:
5f covalency in [U(C 7 H 7 ) 2 ] − was probed with carbon K-edge X-ray absorption spectroscopy (XAS) and electronic structure theory. The results revealed U 5f orbital participation in δ-bonding in both the ground- and core-excited states; additional 5f ϕ-mixing is observed in the core-excited states. Comparisons with U(C 8 H 8 ) 2 show greater δ-covalency for [U(C 7 H 7 ) 2 ] − .
Type of Medium:
Online Resource
ISSN:
1359-7345
,
1364-548X
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2021
detail.hit.zdb_id:
1472881-3