In:
Inorganic Chemistry Frontiers, Royal Society of Chemistry (RSC), Vol. 9, No. 8 ( 2022), p. 1812-1818
Abstract:
A three-dimensional (3D) metal–organic framework constructed from unprecedented Zn 9 O 2 (OH) 2 (pyz) 12 (pyz = pyrazolate) clusters and Ni(salen)-derived linkers was reported. The MOF exhibits high catalytic activity for CO 2 cycloaddition reactions with excellent stability. The MOF catalyst can be recycled at least 15 times without loss of activity and the turnover number (TON) per Ni site can reach as high as 2887.
Type of Medium:
Online Resource
ISSN:
2052-1553
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022