In:
Organic Chemistry Frontiers, Royal Society of Chemistry (RSC), Vol. 9, No. 10 ( 2022), p. 2728-2733
Abstract:
A tetrabutylammonium decatungstate (TBADT)-photocatalyzed direct coupling of inert alkanes and quinoxalin-2(1 H )-ones with H 2 evolution was developed at room temperature. The present transformation achieved direct C(sp 3 )–H/C(sp 2 )–H coupling under noble metal-free, acid-free and oxidant-free conditions. With this method, a series of 3-alkylated quinoxalin-2(1 H )-ones bearing various functional groups were synthesized in good to excellent yields.
Type of Medium:
Online Resource
ISSN:
2052-4129
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
