In:
Journal of Materials Chemistry C, Royal Society of Chemistry (RSC), Vol. 10, No. 34 ( 2022), p. 12316-12322
Abstract:
The use of LED lighting results in a prolonged exposure to blue radiation, which is harmful to the human eye health. Herein, a new strategy aiming for “human-centric” lighting is demonstrated by doping Te 4+ into Cs 2 HfCl 6 , leading to zero blue radiation through mixing red and green phosphors in a NUV-LED chip. Cs 2 HfCl 6 :Te yields an efficient bright yellow emission with a high photoluminescence quantum efficiency of 95.26%. Surprisingly, the emission intensity maintains 96% of its initial value even when the post-annealing temperature is as high as 450 °C, demonstrating superior thermal resistance. Moreover, excellent environmental stability is achieved via a silane coupling agent to modify the surface, and the broadband yellow emission intensity remains at 91% of the initial strength after soaking in water for 100 min and hardly changes after 120 h of storage in air. A packaging device using a 395 nm LED chip, Cs 2 HfCl 6 :0.5%Te, and green and red-emitting phosphors produces warm white light with a high color rendering index, while significantly eliminating blue radiation. These results demonstrate that Cs 2 HfCl 6 :Te perovskite is a promising phosphor with the capability of advancing human-centric lighting.
Type of Medium:
Online Resource
ISSN:
2050-7526
,
2050-7534
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
detail.hit.zdb_id:
2702245-6
