In:
Physical Chemistry Chemical Physics, Royal Society of Chemistry (RSC), Vol. 24, No. 21 ( 2022), p. 13305-13316
Kurzfassung:
Two-dimensional MoS 2 nanosheets have shown great potential in heavy metal remediation due to their unique properties. MoS 2 has two primary phases: 1T and 2H. Each has different physiochemical properties, but the impact of these differences on the overall material's heavy metal removal performance and associated mechanisms is rarely reported. In this study, we synthesized morphologically similar but phase-distinct MoS 2 samples via hydrothermal synthesis, which comprised dominantly either a metallic 1T phase or a semiconducting 2H phase. 1T-MoS 2 samples exhibited higher removal capacities for Ag + and Pb 2+ cations relative to 2H-MoS 2 . In particular, an eight-fold increase in the Pb 2+ adsorption capacity was observed in the 1T-MoS 2 samples ( i.e. ∼632.9 mg g −1 ) compared to the 2H-MoS 2 samples (∼81.6 mg g −1 ). The mechanisms driving the enhanced performance of 1T-MoS 2 were investigated through detailed characterization of metal-laden MoS 2 samples and DFT modelling. We found that 1T-MoS 2 intrinsically had a larger interlayer spacing than 2H-MoS 2 because water molecules were retained between the hydrophilic 1T nanosheets during hydrothermal synthesis. The widened interlayer spacing in 1T-MoS 2 allowed the diffusion of heavy metal ions into the nanochannels, increasing the number of adsorption sites and total removal capacities. On the other hand, DFT modelling revealed the energy-favorable adsorption complex of Ag + and Pb 2+ for 1T-MoS 2 , in which each metal atom was bonded with three S atoms leading to much higher adsorption energies relative to 2H-MoS 2 for Ag + and Pb 2+ . This study unravels the underlying mechanisms of phase-dependent heavy metal remediation by MoS 2 nanosheets, providing an important guide for the use of 2D nanomaterials in environmental applications which include heavy metal removal, contaminant sensing, and membrane separation.
Materialart:
Online-Ressource
ISSN:
1463-9076
,
1463-9084
Sprache:
Englisch
Verlag:
Royal Society of Chemistry (RSC)
Publikationsdatum:
2022
ZDB Id:
1476283-3
ZDB Id:
1476244-4
ZDB Id:
1460656-2
