In:
Green Chemistry, Royal Society of Chemistry (RSC), Vol. 24, No. 20 ( 2022), p. 7883-7888
Abstract:
Herein, we report a rare catalyst-free electrochemical cross-coupling of benzylic C–H bonds with organotrifluoroborates, which readily proceeds at room temperature and provides a unique protocol for forging C(sp 3 )–C(sp 3 ), C(sp 3 )–C(sp 2 ) and C(sp 3 )–C(sp) bonds. In particular, this work discloses the dual role of organotrifluoroborates serving both as a coupling partner and an electrolyte in C(sp 3 )–H functionalization.
Type of Medium:
Online Resource
ISSN:
1463-9262
,
1463-9270
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
detail.hit.zdb_id:
1485110-6
detail.hit.zdb_id:
2006274-6