In:
Chemical Science, Royal Society of Chemistry (RSC), Vol. 13, No. 27 ( 2022), p. 8045-8051
Abstract:
The occurrence of planar hexacoordination is very rare in main group elements. We report here a class of clusters containing a planar hexacoordinate silicon (phSi) atom with the formula SiSb 3 M 3 + (M = Ca, Sr, Ba), which have D 3h ( 1 A 1 ′) symmetry in their global minimum structure. The unique ability of heavier alkaline-earth atoms to use their vacant d atomic orbitals in bonding effectively stabilizes the peripheral ring and is responsible for covalent interaction with the Si center. Although the interaction between Si and Sb is significantly stronger than the Si–M one, sizable stabilization energies (−27.4 to −35.4 kcal mol −1 ) also originated from the combined electrostatic and covalent attraction between Si and M centers. The lighter homologues, SiE 3 M 3 + (E = N, P, As; M = Ca, Sr, Ba) clusters, also possess similar D 3h symmetric structures as the global minima. However, the repulsive electrostatic interaction between Si and M dominates over covalent attraction making the Si–M contacts repulsive in nature. Most interestingly, the planarity of the phSi core and the attractive nature of all the six contacts of phSi are maintained in N-heterocyclic carbene (NHC) and benzene (Bz) bound SiSb 3 M 3 (NHC) 6 + and SiSb 3 M 3 (Bz) 6 + (M = Ca, Sr, Ba) complexes. Therefore, bare and ligand-protected SiSb 3 M 3 + clusters are suitable candidates for gas-phase detection and large-scale synthesis, respectively.
Type of Medium:
Online Resource
ISSN:
2041-6520
,
2041-6539
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
detail.hit.zdb_id:
2559110-1
