In:
Chemical Communications, Royal Society of Chemistry (RSC), Vol. 59, No. 72 ( 2023), p. 10749-10752
Abstract:
The group 7 complexes [M(κ 3 -2,6-(R 2 PO) 2 C 5 H 3 N)(CO) 2 L][BAr F 4 ] [M = Mn, R = i Pr, L = THF; M = Re, R = t Bu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive change of [BAr F 4 ] anions for M = Mn, whereas for M = Re the changes are smaller and also remote to the site of reactivity.
Type of Medium:
Online Resource
ISSN:
1359-7345
,
1364-548X
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2023
detail.hit.zdb_id:
1472881-3
