In:
New Journal of Chemistry, Royal Society of Chemistry (RSC), Vol. 47, No. 12 ( 2023), p. 5953-5960
Abstract:
The reactivity of phenanthro-[9,10]-(1,3,2)-diazadiphospholenes towards iron triad carbonyls has been studied. Diphospholenes were found to react with cobalt octacarbonyl and diiron nonacarbonyl as phosphinyl radicals. Reaction with nickel carbonyl proceeds with the initial coordination of the diphospholenes to the metal ion as Lewis bases. The obtained compounds were characterized by NMR and IR spectroscopy, and their structure was established using X-ray structural analysis. DFT computational studies investigated the bonding nature in new compounds.
Type of Medium:
Online Resource
ISSN:
1144-0546
,
1369-9261
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2023
detail.hit.zdb_id:
1472933-7