In:
Organic Chemistry Frontiers, Royal Society of Chemistry (RSC)
Abstract:
Herein, a direct radical borylation of alkenyl triflates with Lewis base-ligated boranes (LB-BH 3 ) was accomplished, affording a series of α-boryl carbonyl compounds. This process was triggered by the photoinduced homolytic cleavage of alkenyl triflates to generate the CF 3 radical as a HAT species, thus obviating the need for an external radical initiator or a photocatalyst.
Type of Medium:
Online Resource
ISSN:
2052-4129
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2023