In:
Synthesis, Georg Thieme Verlag KG, Vol. 51, No. 05 ( 2019-03), p. 1196-1206
Abstract:
GlucoSiFA derivatives bearing an azide or alkynyl side chain were obtained from peracetyl-d-glucose using as key step a tosylate substitution by a SiFA thiolate obtained from 4-(di-tert-butylfluorsilyl)benzenethiol. In analogy, two-fold SiFA-substituted maltose and lactose derivatives were synthesized via bistosylates. Introduction of an acetal-protecting group in β-d-azidolactose allowed the synthesis of a LactoSiFA derivative bearing only one SiFA moiety.
Type of Medium:
Online Resource
ISSN:
0039-7881
,
1437-210X
DOI:
10.1055/s-0037-1611656
Language:
English
Publisher:
Georg Thieme Verlag KG
Publication Date:
2019
detail.hit.zdb_id:
204080-3
detail.hit.zdb_id:
2033062-5
