In:
Synthesis, Georg Thieme Verlag KG
Abstract:
Deoxygenative alkylation of benzyl alcohols was realized by using acetate as the alcohol activation group. The C–O bond homolysis is achieved by a boryl radical-promoted β-scission process. The strategy is amenable to a variety of benzyl alcohols, including primary, secondary, and more challenging tertiary alcohols. The synthetic practicability was demonstrated by a gram-scale one-pot reaction.
Type of Medium:
Online Resource
ISSN:
0039-7881
,
1437-210X
DOI:
10.1055/s-0042-1751463
Language:
German
Publisher:
Georg Thieme Verlag KG
Publication Date:
2023
detail.hit.zdb_id:
204080-3
detail.hit.zdb_id:
2033062-5