In:
The Journal of Chemical Physics, AIP Publishing, Vol. 36, No. 12 ( 1962-06-15), p. 3440-3444
Abstract:
The magnetic susceptibility of ReF6 has been measured in the range 4°—296°K using the Faraday method. The susceptibility in the range 14°—296°K can be expressed by means of χReF6M=(78±1)×10−4/T+(0.87±0.03)×10−4,from which one calculates a moment of 0.25 Bohr magnetons. Applying a theory developed for gaseous ReF6 [W. Moffitt, G. L. Goodman, M. Fred, and B. Weinstock, Mol. Phys. 2, 109 (1959)] to the magnetic measurements reported here gives ζ=3160 cm—1 and 10Dq/α=55 000 cm—1, where α is an orbital reduction parameter connecting the dl2g and deg levels. The diamagnetic susceptibility of WF6 has been remeasured and preliminary measurements on TcF6 are reported.
Type of Medium:
Online Resource
ISSN:
0021-9606
,
1089-7690
Language:
English
Publisher:
AIP Publishing
Publication Date:
1962
detail.hit.zdb_id:
3113-6
detail.hit.zdb_id:
1473050-9
