In:
Australian Journal of Chemistry, CSIRO Publishing, Vol. 65, No. 3 ( 2012), p. 320-
Abstract:
Via hydrothermal synthesis, we constructed four nucleobase metal-organic compounds, viz. Zn2(7H-ade)(oba)2·H2O (1), Zn(1H-hyp)(Hoba) (2), Ni(1H-ade)(ip) (3), and Cd(H2O)(9H-ade)(ip) (4), where ade, hyp, H2oba, and H2ip are adenine, hypoxanthine, 4,4′-oxybisbenzoic acid, and isophthalic acid, respectively. These polymers show novel 2D and 3D structures, such as 3-fold interpenetrating dmp net, supramolecular zeolite-type sra net, and exceptional 2D 44 net composed of three kinds of quadrangle, observed in polymers 1, 2, and 3, respectively. Moreover, thermogravimetric studies of polymers 1, 2, and 4, and the magnetic properties of 3 are also explored.
Type of Medium:
Online Resource
ISSN:
0004-9425
Language:
English
Publisher:
CSIRO Publishing
Publication Date:
2012
