In:
Nanotechnology, IOP Publishing, Vol. 33, No. 34 ( 2022-08-20), p. 345401-
Kurzfassung:
Synthesis of NiHCCo precursors via simple co-precipitation and nickel–cobalt tetraselenide composites grown on nitrogen-doped reduced graphene oxide (NiCoSe 4 /N-rGO) were fabricated using solvothermal method. The introduction of N-rGO used as a template effectively prevented agglomeration of NiCoSe 4 nanoparticles and provided more active sites, which greatly increased the electrochemical and electrical conductivity for NiCoSe 4 /N-rGO. NiCoSe 4 /N-rGO-20 presents a remarkably elevated specific capacity of 120 mA h g −1 under current density of 1 A g −1 . NiCoSe 4 /N-rGO-20 demonstrates an excellent cycle life and achieves a remarkable 83% retention rate over 3000 cycles with 10 A g −1 . NiCoSe 4 /N-rGO-20//N-rGO asymmetric supercapacitor was constructed based on the NiCoSe 4 /N-rGO-20 as an anode, N-rGO as cathode by using 2 mol l −1 KOH as an electrolyte. NiCoSe 4 /N-rGO-20//N-rGO ASC demonstrates an ultra-big energy density of 14 Wh kg −1 and good circulation stability in the power density of 902 W kg −1 . It is doubled in comparison to the NiCoSe 4 /N-rGO-20//rGO asymmetric supercapacitor (7 Wh kg −1 ). The NiCoSe 4 /N-rGO-20//N-rGO ASC capacity retention is still up to 93% over 5000 cycles (5 A g −1 ). The results reveal that this device would be a prospective cathode material of supercapacitors in actual applications.
Materialart:
Online-Ressource
ISSN:
0957-4484
,
1361-6528
DOI:
10.1088/1361-6528/ac6ff2
Sprache:
Unbekannt
Verlag:
IOP Publishing
Publikationsdatum:
2022
ZDB Id:
1362365-5
SSG:
11
