In:
Acta Crystallographica Section E Structure Reports Online, International Union of Crystallography (IUCr), Vol. 64, No. 9 ( 2008-09-01), p. m1162-m1163
Abstract:
The title compound, {[Mn(NH 2 C 6 H 4 SO 3 ) 2 (H 2 O) 2 ]·2H 2 O} n , was prepared under mild hydrothermal conditions. The unique Mn II ion is located on a crystallographic inversion center and is coordinated by two –NH 2 and two –SO 3 groups from four 4-aminobenzenesulfonate ligands and by two water molecules in the axial positions, forming a slightly distorted octahedral coordination environment. The 4-aminobenzenesulfonate anions behave as μ 2 -bridging ligands to produce a two-dimensional structure. In the crystal structure, intermolecular N—H...O, O—H...O and C—H...O hydrogen bonds link the layers into a three-dimensional network.
Type of Medium:
Online Resource
ISSN:
1600-5368
DOI:
10.1107/S1600536808025579
DOI:
10.1107/S1600536808025579/lh2671sup1.cif
DOI:
10.1107/S1600536808025579/lh2671sup0.html
DOI:
10.1107/S1600536808025579/lh2671Isup2.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2008
detail.hit.zdb_id:
2843762-7
detail.hit.zdb_id:
2041947-8