In:
Acta Crystallographica Section E Structure Reports Online, International Union of Crystallography (IUCr), Vol. 70, No. 11 ( 2014-11-01), p. 421-423
Abstract:
In the molecular structure of the dinuclear title compound [η 5 -(C 5 (CH 3 ) 5 )(CO)Fe{(μ-BCl)(μ-CO)}PtCl(P(C 6 H 11 ) 3 )]·C 6 H 6 , the two metal atoms, iron(II) and platinum(II), are bridged by one carbonyl (μ-CO) and one chloridoborylene ligand (μ-BCl). The Pt II atom is additionally bound to a chloride ligand situated trans to the bridging borylene, and a tricyclohexylphosphane ligand (PCy 3 ) trans to the carbonyl ligand, forming a distorted square-planar structural motif at the Pt II atom. The Fe II atom is bound to a pentamethylcyclopentadienyl ligand [η 5 -C 5 (CH 3 ) 5 ] and one carbonyl ligand (CO), forming a piano-stool structure. Additionally, one benzene solvent molecule is incorporated into the crystal structure, positioned staggered relative to the pentamethylcyclopentadienyl ligand at the Fe II atom, with a centroid–centroid separation of 3.630 (2) Å.
Type of Medium:
Online Resource
ISSN:
1600-5368
DOI:
10.1107/S1600536814023381
DOI:
10.1107/S1600536814023381/wm5073sup1.cif
DOI:
10.1107/S1600536814023381/wm5073Isup2.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2014
detail.hit.zdb_id:
2843762-7
detail.hit.zdb_id:
2041947-8
