In:
Acta Crystallographica Section C Structural Chemistry, International Union of Crystallography (IUCr), Vol. 78, No. 3 ( 2022-03-01), p. 137-140
Abstract:
The nickel chloride complex of the Schiff base N 2 , N 2′ -propanediylbis(2,3-butanedione-2-imine-3-oxime), namely, chlorido(3,9-dimethylundeca-3,8-diene-2,10-dione 10-oxime 2-oximato-κ 4 N , N ′, N ′′, N ′′′)nickel(II), [NiCl(C 11 H 19 N 4 O 2 )], at 100 K crystallizes in the orthorhombic space group Cmce . The structure exhibits mirror disorder of the main molecule that is not present in the bromide analogue. The relatively small number of unique reflections in the data set and the disorder imposed by the crystallographic mirror plane present a challenging educational case study.
Type of Medium:
Online Resource
ISSN:
2053-2296
DOI:
10.1107/S2053229622000973
DOI:
10.1107/S2053229622000973/zo3017sup1.cif
DOI:
10.1107/S2053229622000973/zo3017Isup2.hkl
DOI:
10.1107/S2053229622000973/zo3017sup3.pdf
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2022
detail.hit.zdb_id:
2025703-X