In:
Acta Crystallographica Section E Crystallographic Communications, International Union of Crystallography (IUCr), Vol. 75, No. 7 ( 2019-07-01), p. 1011-1014
Abstract:
In the crystal structure of the isostructural title compounds, namely {2,6-bis[(di- tert -butylphosphanyl)oxy]-4-hydroxyphenyl}chloridopalladium(II), [Pd(C 22 H 39 O 3 P 2 )Cl], 1 , and {2,6-bis[(di- tert -butylphosphanyl)oxy]-4-hydroxyphe nyl}chloridoplatinum(II), [Pt(C 22 H 39 O 3 P 2 )Cl], 2 , the metal centres are coordinated in a distorted square-planar fashion by the POCOP pincer fragment and the chloride ligand. Both complexes form strong hydrogen-bonded chain structures through an interaction of the OH group in the 4-position of the aromatic POCOP backbone with the halide ligand.
Type of Medium:
Online Resource
ISSN:
2056-9890
DOI:
10.1107/S2056989019008491
DOI:
10.1107/S2056989019008491/rz5258sup1.cif
DOI:
10.1107/S2056989019008491/rz52581sup2.hkl
DOI:
10.1107/S2056989019008491/rz52582sup3.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2019
detail.hit.zdb_id:
2843762-7
detail.hit.zdb_id:
2041947-8