In:
Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena, American Vacuum Society, Vol. 17, No. 5 ( 1999-09-01), p. 1935-1940
Abstract:
The solid-solid chemical reactions of phenols or ketones, such as β-naphthol (1) or anthron (2), with FeCl3⋅6H2O by ultraviolet irradiation give coupling dimeric products. The mechanisms are studied using atomic force microscopy (AFM) and known crystal packing data. AFM reveals that the crystal face (100) of 2 or (001) of 1 exhibits stumpy protrusions all over the surface from the contact edge of the crystals, respectively, whereas the long side face (010) of 2 gives volcanoes. All of those are guided by the crystal structure. Molecular interpretations of the AFM features are given.
Type of Medium:
Online Resource
ISSN:
1071-1023
,
1520-8567
Language:
English
Publisher:
American Vacuum Society
Publication Date:
1999
detail.hit.zdb_id:
3117331-7
detail.hit.zdb_id:
3117333-0
detail.hit.zdb_id:
1475429-0