In:
Japanese Journal of Applied Physics, IOP Publishing, Vol. 31, No. 9R ( 1992-09-01), p. 2791-
Abstract:
Emission and excitation spectra and luminescence decay times of the SrS:Sb 3+ and SrSe:Sb 3+ powder phosphors are studied over the temperature range from 2 to 372 K. The emission band at 293 K is located at 600 nm for SrS:Sb 2 S 3 (0.05 mol%) and at 633 nm for SrSe:Sb 2 S 3 (0.2 mol%). The excitation processes are attributed to three transitions; (i) the intraionic transitions within Sb 3+ , (ii) the charge transfer transition from the host anion to Sb 3+ and (iii) the fundamental absorption by host crystal, followed by the transfer of the excitation energy to an unexcited Sb 3+ ion. The shape of the excitation spectrum of the intraionic transitions is similar to those of the absorption spectra of Tl + -type ions in alkali halides. The results are compared with those of MgS:Sb 3+ , CaS:Sb 3+ , CaSe:Sb 3+ and SrS:Bi 3+ .
Type of Medium:
Online Resource
ISSN:
0021-4922
,
1347-4065
DOI:
10.1143/JJAP.31.2791
Language:
Unknown
Publisher:
IOP Publishing
Publication Date:
1992
detail.hit.zdb_id:
218223-3
detail.hit.zdb_id:
797294-5
detail.hit.zdb_id:
2006801-3
detail.hit.zdb_id:
797295-7