In:
Laser Chemistry, Hindawi Limited, Vol. 15, No. 1 ( 1994-01-01), p. 61-69
Abstract:
A homemade TEA CO 2 laser tuned to the 1OP(48) line, 10.91 μm, was used to excite the v 4 mode of CDCl 3 (914 cm -1 ). The IR fluorescence signal from the CDCl 3 2 v 5 overtone band (1492 cm -1 ) was isolated by means of a gaseous filter. The temporal variation of this fluorescence emission was studied as a function of the laser fluence. Under high excitation conditions, non-linear effects become obvious, and measured rate constants greater than predicted from linear kinetic rate equations have been found.
Type of Medium:
Online Resource
ISSN:
0278-6273
,
1476-3516
Language:
English
Publisher:
Hindawi Limited
Publication Date:
1994
detail.hit.zdb_id:
2035640-7