In:
Pure and Applied Chemistry, Walter de Gruyter GmbH, Vol. 84, No. 3 ( 2011-09-30), p. 675-684
Abstract:
Synthesis of unsymmetrical organic carbonates by transesterification of various alcohols with diethyl carbonate (DEC) is an interesting topic in green chemistry. In this work, we synthesized a kind of zirconium phosphonate functionalized with pendent N -SO 3 H group by the reaction of ZrOCl 2 ·8H 2 O with N , N -bis(phosphonomethyl)-sulfamic acid, which was formed from sulfamic acid through a Mannich-type reaction. The functionalized zirconium phosphonate was characterized by Fourier transform/infrared (FT/IR), N 2 adsorption and desorption, scanning electron microscopy (SEM), and powder X-ray diffraction (XRD) techniques, and was used as the heterogeneous catalyst for the synthesis of unsymmetrical organic carbonates by transesterification of various alcohols with DEC. It was demonstrated that the catalyst is very active and selective for the reactions, and very high yields of the desired products could be obtained. In addition, the catalyst could be easily recovered and the decrease in catalytic activity and selectivity was minor after three-fold usage. The mechanism for the transesterification reactions is discussed.
Type of Medium:
Online Resource
ISSN:
1365-3075
,
0033-4545
DOI:
10.1351/PAC-CON-11-06-04
Language:
Unknown
Publisher:
Walter de Gruyter GmbH
Publication Date:
2011
detail.hit.zdb_id:
2022101-0
