In:
Zeitschrift für Kristallographie - Crystalline Materials, Walter de Gruyter GmbH, Vol. 229, No. 12 ( 2014-12-1), p. 807-822
Abstract:
In this report, we summarize our experimental and theoretical investigations in the zinc(II) imidazolate, [Zn(im) 2 ], and zinc(II) 4,5-dichloroimidazolate, [Zn(dcim) 2 ], systems that have been published previously. This comprises a study on the thermodynamic stabilities of the two densest phases with coi and zni framework structures in the [Zn(im) 2 ] system including the discovery and characterization of a new [Zn(im) 2 ·0.5py]-neb phase (py = pyridine), a study on the mechanism of formation of the [Zn(im) 2 ]-zni phase as well as a study on the discovery and characterization of a new [Zn(dcim) 2 ]-SOD phase. In addition, we present as yet unpublished work. This concerns the discovery and characterization of a new [Zn(im) 2 ·0.5mor]-neb phase (mor = morpholine) and investigations of the mechanisms of crystallization of [Zn(im) 2 ·0.5py]-neb and [Zn(im) 2 ·0.5mor]-neb as well as an evalutation of time-resolved SAXS/WAXS data recorded in-situ during the formation of [Zn(im) 2 ]-zni.
Type of Medium:
Online Resource
ISSN:
2196-7105
,
2194-4946
DOI:
10.1515/zkri-2014-1788
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2014
SSG:
13