In:
Zeitschrift für Kristallographie - Crystalline Materials, Walter de Gruyter GmbH, Vol. 234, No. 9 ( 2019-09-25), p. 613-621
Abstract:
The molecular and single crystal structure of O , O -diethyl O -[2-(dimethylamino)ethyl] phosphorothioate oxalate, as determined by single crystal X-ray diffraction studies, is described for the first time; although this compound is well-known by industry and research from the mid-20 th century. The known decomposition product of pure O , O -diethyl O -[2-(dimethylamino)ethyl] phosphorothioate could also be structurally characterized. Additionally, the compounds are characterized by recent analytical methods e.g. NMR. The findings of our study support the thesis that the isolated decomposition product must be a by-product of the thiono-thiolo rearrangement process of the title compound.
Type of Medium:
Online Resource
ISSN:
2196-7105
,
2194-4946
DOI:
10.1515/zkri-2019-0025
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2019
SSG:
13