In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 25, No. 5 ( 1970-5-1), p. 476-479
Abstract:
The reactions of Uranium pentaethoxide with 1,3 dicarbonyl ligands (dibenzoyl methane, ethyl 1-methyl acetoacetate, 5,5 dimethyl 1,3 cyclohexane dione (dimedone) have been studied under anhydrous conditions and the derivatives of the type U(OEt) 5-x (lig) x (where x= 1, 2 or 3) have been isolated. These derivatives interchange their ethoxy groups with tertiary butoxy groups when treated with tertiary butanol. Determination of molecular weight of soluble derivatives suggest them to be monomeric in boiling benzene.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1970-0506
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1970
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5