In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 45, No. 7 ( 1990-7-1), p. 1010-1018
Abstract:
31 P and 125 Te NMR data of trialkylphosphane tellurides are compared. The deviation of the shifts for Me 3 PTe and 'Bu 3 PTe from those of other phosphane tellurides is interpreted in terms of high s-character of the P–Te bond originating from the phosphorus (R = Me) and the tellurium (R = 'Bu) atom, respectively. The molecular structure of 'Pr 3 PTe has been determined by X-ray crystallography (P–Te 2.365 A). A reduction of the bond order is suggested based also on a comparison of the R 3 PSe and R 3 PTe NMR data.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1990-0717
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1990
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5