In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 50, No. 2 ( 1995-2-1), p. 159-167
Abstract:
The crystal structures of the thioether complexes [MCl 4 (SEt 2 ) 2 ] with M = Mo and W have been solved by X-ray methods. Both compounds crystallize isotypically in the triclinic space group P1̄ with two formula units per cell unit. The metal atoms are octahedrally coordinated by four chlorine atoms and by the two sulfur atoms of the thioether molecules in transposition (symmetry C i ) with bond lengths (average): Mo-Cl 233.1, Mo-S 253.4, W-Cl 233.1, and W-S 251.7 pm. Both complexes were also characterized by 1 H and 13 C NMR spectroscopy as well as by measurement of the magnetic susceptibilities in the temperature range from 1.8 to 350 K.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1995-0201
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1995
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5