In:
Zeitschrift für Kristallographie, Walter de Gruyter GmbH, Vol. 222, No. 2 ( 2007-02), p. 99-104
Abstract:
Two N-substituted phenylene diamines, C 30 H 28 N 2 S 2 O 4 (I) and C 30 H 28 N 2 S 2 O 5 (II), have been synthesized, and characterized by spectroscopic and single crystal X-ray analyses. Intermolecular N—H···O and C—H···O hydrogen bonds link the molecules of (I) into centrosymmetric dimers, which are further joined by C—H···O hydrogen bonds to form one-dimensional polymeric chain propagating along the [100] direction. The two molecules, A and B, in the asymmetric unit of (II) are connected by a pair of N—H···O hydrogen bonds forming a characteristic R 2 2 (14) dimeric ring centered at (0.245, 0.510, 0.252). The interlinking of adjacent dimers in (II) via C—H···O hydrogen bonds generates infinite one-dimensional ABBAAB… polymeric chain along the [101] direction.
Type of Medium:
Online Resource
ISSN:
0044-2968
DOI:
10.1524/zkri.2007.222.2.99
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2007
SSG:
13