In:
Journal of Materials Research, Springer Science and Business Media LLC, Vol. 32, No. 21 ( 2017-11-14), p. 4087-4094
Abstract:
Zinc oxide (ZnO) layers and nanowires were grown by chemical vapor deposition (CVD) using methane (CH 4 ) as reducing agent. Compared to conventional CVD processes, which commonly use graphite powder to reduce the ZnO powder source material, this low-cost method allows an improved controllability of the growth processes. Specifically, the consumption of the source material–a commercially available ZnO powder–can be controlled in a very precise way by varying the flow of the reducing CH 4 or the re-oxidizing O 2 . Using this parameter, the growth can be switched between ZnO layers and nanostructures. High-quality ZnO layers have been grown on gallium nitride (GaN) substrates and on c -plane sapphire with an intermediate aluminum nitride (AlN) nucleation layer. By adjusting the growth conditions accordingly, ZnO nanowires were also grown with this method catalyst-free using a - and c -plane sapphire with ZnO nucleation layer as a substrate. The optical properties of the nanowires were investigated by low-temperature photoluminescence (PL) and compared to samples grown by conventional carbo-thermal CVD.
Type of Medium:
Online Resource
ISSN:
0884-2914
,
2044-5326
DOI:
10.1557/jmr.2017.280
Language:
English
Publisher:
Springer Science and Business Media LLC
Publication Date:
2017
detail.hit.zdb_id:
54876-5
detail.hit.zdb_id:
2015297-8
