In:
Frontiers in Chemistry, Frontiers Media SA, Vol. 9 ( 2021-2-19)
Kurzfassung:
A three-dimensional (3D) Silverton-type polyoxomolybdate (POMo) with the formula of NH 4 {Mn 4 [PrMo 12 O 42 ]}·18H 2 O (1) was successfully isolated and well characterized by single crystal X-ray diffraction, X-ray powder diffraction pattern, infrared spectrum, thermogravimetric and elemental analyses. The inorganic building block {PrMo 12 O 42 } has formed 3D frameworks via the {MnO 6 } linker. The excitation of compound 1 in solid state at 375 nm displays red emission. Moreover, variable temperature magnetic susceptibility measurements indicate that the magnetic behavior in compound 1 is dominated by antiferromagnetic interactions.
Materialart:
Online-Ressource
ISSN:
2296-2646
DOI:
10.3389/fchem.2021.615595
DOI:
10.3389/fchem.2021.615595.s001
Sprache:
Unbekannt
Verlag:
Frontiers Media SA
Publikationsdatum:
2021
ZDB Id:
2711776-5