In:
International Journal of Molecular Sciences, MDPI AG, Vol. 23, No. 24 ( 2022-12-08), p. 15538-
Abstract:
The fact of the fracture of the extraction curve of lanthanides by 1,10-phenanthroline-2,9-diamides is explained in terms of the structure of complexes, solvent extraction data and quantum chemical calculations. The solvent extraction proceeds in two competing directions: in the form of neutral complexes LLn(NO3)3 and in the form of tight ion pairs {[LLn(NO3)2 H2O]+ (NO3−).
Type of Medium:
Online Resource
ISSN:
1422-0067
DOI:
10.3390/ijms232415538
Language:
English
Publisher:
MDPI AG
Publication Date:
2022
detail.hit.zdb_id:
2019364-6
SSG:
12
