In:
Inorganics, MDPI AG, Vol. 11, No. 5 ( 2023-04-25), p. 186-
Kurzfassung:
Hydrogen is considered as a clean energy carrier able to achieve the decarbonization of the economy, but its compact, safe, and efficient storage represents an important challenge. Among many materials forming hydrides, this work reports the study of hydrogen sorption properties of a novel bcc high-entropy alloy, Ti0.30V0.25Mn0.10Zr0.10Nb0.25, synthesized by arc melting. In less than 60 s, the alloy fully absorbs hydrogen at room temperature, reaching a capacity of 2.0 H/M (2.98 wt.%). A two-step reaction with hydrogen is confirmed by pressure-composition isotherms, synchrotron X-ray and neutron diffraction: bcc solid solution ↔ bcc monohydride ↔ fcc dihydride. For the second step transformation, the calculated thermodynamic values indicate the formation of a very stable dihydride, with ΔHabs = −97 kJ/molH2. Moreover, the pair distribution function analysis of high-energy synchrotron X-ray scattering data validates a completely random distribution of metal atoms in the fcc dihydride phase, without noticeable lattice strain nor elemental segregation. In situ synchrotron X-ray and neutron diffraction, performed during hydrogen desorption by heating under vacuum, demonstrated full reversibility of the reaction with hydrogen. On the basis of these results, tuning the chemical composition of high-entropy alloys may have great implications in terms of hydrogen sorption properties.
Materialart:
Online-Ressource
ISSN:
2304-6740
DOI:
10.3390/inorganics11050186
Sprache:
Englisch
Verlag:
MDPI AG
Publikationsdatum:
2023
ZDB Id:
2735043-5
